There is another forum
http://www.statuaryplace.com/discussion/
discussion.html which specialises in questions of your type and you can also hook up with premade molds, there a wide variety of fountain molds out there to experiment with. If you then have something unique in mind, you might be better off getting the help of a local sculptor and mold maker for your first one.
There are many techniques and materials, each one has its merits and retail price points - poured concrete is the least cost, most difficult to finish nicely, and extremely heavy - a cubic foot of concrete is well over 100 lbs.